Chemistry
New study reveals how tiny molecules are kept out by special filters
Researchers found that a common filter technology can effectively remove toxic chemicals from water when they're hydrated, but not as well when they're dry.
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1 min read
The Role of Hydration in Removing Glyphosate and Aminomethylphosphonic Acid from Water
Nanofiltration membranes can remove glyphosate and aminomethylphosphonic acid from water through steric, Donnan, and dielectric exclusions. However, the significance of dielectric exclusion resulting from hydration has not been fully understood. Researchers Trinh PB et al. investigated the properties of hydration in this context to elucidate its role.
The study found that charge and dielectric exclusions are dominant in membranes with molecular weight cut-off greater than 150 Da. When glyphosate and aminomethylphosphonic acid are present in neutral forms, partial removal occurs, especially in membranes with this high MWCO at pH 2. However, when these compounds are negatively charged, their removal increases.
The researchers observed that the hydration layer can be shredded at higher applied pressures, leading to decreased removal rates. The study suggests that understanding the role of hydration is crucial for tuning nanofiltration membranes for effective water purification.
This research highlights the importance of considering the complex interactions between molecules and membrane materials in determining their effectiveness. As we continue to develop technologies to remove pollutants from our environment, it is essential to grasp the intricacies of these processes, just as the researchers have done in this study. By doing so, we can create more efficient systems for water purification, ultimately contributing to a cleaner and healthier world.
1 min read
Imagine walking into a garden filled with vibrant flowers and lush greenery, but what if you also had to wade through a stream of toxic chemicals that were once used to make your food crops grow? The good news is that scientists have been working on finding ways to clean these pollutants out of our water sources. Recently, researchers discovered that something as simple as the way water interacts with tiny filters – called nanofiltration membranes – can be crucial in removing certain toxins from our drinking water.
These membranes are like tiny sieves that catch particles too small for us to see, and they're especially good at filtering out chemicals like glyphosate (a weed killer) and aminomethylphosphonic acid (a pesticide). But what's happening on a much smaller scale – at the molecular level – is just as important. The researchers found that when these membranes come into contact with water, something called hydration happens, where tiny layers of water molecules form around the chemicals. This process helps filter out the toxins more efficiently.
What this discovery means is that scientists can now start to tweak and improve these nanofiltration membranes so they're even better at removing pollutants from our water sources. By understanding how these tiny filters work with water, researchers hope to create cleaner drinking water for communities around the world.
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Imagine drinking a glass of water that's been filtered to make it safe from tiny pollutants called glyphosate and aminomethylphosphonic acid. Scientists have discovered how this filtration works, and it's all about the way water molecules cling to these pollutants.
When water passes through a special filter called nanofiltration, it can trap these pollutants using a few different ways: by sticking to them like glue, by creating a kind of wall that keeps them out, or by weakening their charge so they don't fit through. But one way in particular is especially important: the layer of water molecules around the pollutants. When this layer gets "shredded" with higher pressure, it lets the pollutants slip through more easily. This discovery helps us understand how to make these filters even better at keeping our water clean.
The people behind the work
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Trinh PB et al.
Author
Published in Nature communications
Source: Nature communications
Sources & Verification
Every statement in this story is drawn from the facts below. Each is linked to a primary or reputable source — follow any citation to check it for yourself.
- Nanofiltration can remove glyphosate (GLY) and aminomethylphosphonic acid (AMPA) from water via steric, Donnan, and dielectric exclusions, although the significance of dielectric exclusion resulting from hydration has not been elucidated. Nature communications
- This study investigates the properties of hydration and its role in GLY/AMPA removal. show that charge and dielectric exclusions are dominant in membranes with molecular weight cut-off (MWCO) > 150 Da. Nature communications
- The contribution of dielectric exclusion is evident when GLY and AMPA in neutral forms are partially removed (50-80%) with >150 Da membranes at pH 2. Nature communications
- When GLY/AMPA are negatively charged (pH from 4 to 12), GLY/AMPA removal increased from 50-80 to 90%, indicating the growing contribution of both charge and dielectric exclusions. Nature communications
- The hydration layer can be shredded at higher applied pressures, decreasing removal from 86 to 28% (GLY) and 27 to 7% (AMPA). Nature communications
- Both molecular dynamics and Fourier-transform infrared spectroscopy (FTIR) agree on the strong hydration of GLY/AMPA especially at pH 4-6. Nature communications
- Understanding the role of hydration in the removal of small and charged organic micropollutants is important for tuning NF membranes for water purification. Nature communications
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