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Chemistry

New Battery Material Reduces Lithium Waste

A cheaper, sturdier battery with more cycling life is being developed by reducing the amount of lithium needed.

Illustration: Blue Dot News

1 min read

In the pursuit of a more efficient and reliable energy storage system, researchers have made a breakthrough in the development of lithium metal batteries. These batteries hold great promise due to their high theoretical specific energy, which is made possible by the high theoretical specific capacity of lithium metal.

The challenge lies in translating this potential into practical reality. To achieve this, scientists have created a multicomponent solid-solution alloy that combines lithium with other elements. By carefully balancing these elements, they were able to facilitate inward lithium transport into the metal foil, rather than its typical surface deposition. This innovative approach has resulted in a dendrite-free negative electrode.

This achievement marks an important step towards developing safe and durable high-energy-density lithium metal batteries. The potential for such batteries is vast, and researchers like Wang J et al. are bringing us closer to harnessing their power.

The people behind the work

  • Wang J et al.

    Author

    Published in Nature communications

Source: Nature communications

Sources & Verification

Every statement in this story is drawn from the facts below. Each is linked to a primary or reputable source — follow any citation to check it for yourself.

  1. Lithium metal batteries possess the high theoretical specific energy owing to the high theoretical specific capacity of lithium metal. Nature communications
  2. However, practical implementations necessitate a reduction in both lithium mass fraction and lithium utilization within the negative electrode to enhance cycling life and suppress dendrite formation, resulting in a practical reversible capacity of only 30 - 50% of the theoretical value. Nature communications
  3. Herein, we present a lithium metal-based multicomponent solid-solution alloy comprising approximately 90 wt.% lithium, with equal atomic ratios of cadmium, silver, magnesium, and aluminium constituting the remaining 10 wt.%. Nature communications
  4. The increased mixing entropy enables high lithium-atom diffusivity, facilitating inward lithium transport into the metal foil rather than the surface deposition typically observed in conventional lithium metal negative electrodes, while simultaneously promoting a thermodynamically stable (110) crystal facet. Nature communications
  5. These factors collectively yield a dendrite-free negative electrode with a reversible specific capacity of 3100 mAh g -1 . Nature communications
  6. One-ampere-hour pouch cells employing this negative electrode and a LiNi 0.8 Co 0.1 Mn 0.1 O 2 positive electrode achieve an specific energies of 385 Wh kg -1 (based on the total mass of the pouch cell) with 82% capacity retention over 600 cycles. Nature communications
  7. This achievement highlights the potential of this alloy negative electrode to enable safe and durable high-energy-density lithium metal batteries for practical applications. Nature communications

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